Yes, grant is right. Aluminium expands more than steel. So heating it up will make it tighter unless you can get some heat into the ring very quickly before the aluminium has a chance to heat up.
Cooling the wheel down should make the ring gear looser - well, if not loose, then less tight.
If you have a big enough freezer, chuck the wheel in there for a while. If not, go and have a chat to your nearest place with a freezer room (eg. frozen food seller) and ask if you can leave the wheel in their freezer room overnight. Bulk frozen food storage warehouses are about -40 deg, so a lot colder than your home freezer. Take your tools with you when you go to pick it up and give it a try while it's still very cold. If it's still stubborn, give the ring gear a quick run-around with a gas torch. You may be able to get some heat into the ring while the hub is still at freezer temp.