Nick,
Not everyone has the luxury of a freshly, expertly overhauled engine/cylinder head. That your valve clearances have not changed comes as no surprise to me, the modern materials that Keith, Red, I and others use offer far more reliability and longevity than the originals ever could.
There are more old beaters of dubious provenance out there than well-overhauled specimens with precise recent history, advising to leave everything well alone is a rather dangerous move imho. FYI, Laverda specified primary chain replacement at 25000km intervals, for the much-lauded thick-pin Regina chain of the time, at that! Of course wear and tear will vary across a wide spectrum, the wannabe boy-racer will manage to trash his bike far earlier than the sedate tourer. At an educated guess, the stated 25000km would be well on the safe side, but personally I wouldn't run a primary chain for much more than 35000-40000km (unless the bike is pampered of course, reckon a triplex primary can easily last up to 100000km if the bike is cared for and isn't pushed hard). At this stage, the primary chains become quite audible, irrespective of manufacturer, further use would only cause unnecessary wear on the sprockets on which the chain runs, making life harder for the next replacement chain. I replace my own timing chains at around 60000km, don't really feel the need to experience valve salad. The factory never specified replacement intervals for that, maybe they weren't expecting the bikes to last that long?
Out of interest, I have cut several old, tired primary chains apart to inspect actual wear. At around 30000km, distinct wear can be found at each and every pin/sideplate, it doesn't get any better with age. The surest indicator for wear is how far the chain can be "bent" when laid flat. This is a bit misleading in regard to the primary chain being endless, but the difference between a new and old chain can be startling. With the degreased chain laid flat, just pushing and pulling on the links of an old chain will reveal distinct movement between the links, a new chain, also degreased, will show next to no movement.
I'm also convinced that chain technology has progressed a bit since the original Regina chains were fitted. I have yet to see a sheared off pin, but lots of sideplates that have been ripped apart at the pin bore. This is most probably the reason that pins are a lot thinner these days, affording the sideplates the much needed increase in cross-section. This still doesn't make modern chains immune to wear.
piet