Cam,
Thanks for the correction, My memory is clearly not as good as it was and I have confused the transition from the ductile to britle failure mechanism with the glass transition temperature. Extract below refers to the Liberty ships, as you point out the Titanic was rivetted.
The grade of steel used to make Liberty ships suffered from embrittlement, in which materials become brittle. Ships operating in the North Atlantic were often exposed to temperatures below a critical temperature, which changed the failure mechanism from ductile to brittle. Because the hulls were welded together, the cracks could propagate across very large distances; this would not have been possible in riveted ships.